Studying the Interaction of Pirarubicin with DNA and Determining Pirarubicin in Human Urine Samples: Combining Excitation -Emission Fluorescence Matrices with Second-order Calibration Methods

In this paper, UV–vis spectroscopy and fluorescence were combined to study the binding of Calf thymus DNA (ct-DNA) with the anthacycline antibiotic drug pirarubicin (THP). Ethidium bromide (EB) as the fluorescence probe was used to study the competitive binding interactions of THP with DNA by excitation -emission fluorescence matrices (EEFMs) coupled with the parallel factor analysis (PARAFAC) and the alternating normalization-weighted error algorithm (ANWE) with the second-order advantage. All the results conformed that THP mainly bound with DNA by intercalation. Meanwhile, the two second-order calibration methods have been successfully applied to quantify THP in urine samples. Figures of merit were applied to compare the performance of the two methods. The results presented in this work showed that both the PARAFAC and ANWE methods were the convincing way to be applied in the complex biological systems even in the presence of uncalibrated interferences.     

Simultaneous determination of nitroaromatic compounds in water using capillary electrophoresis with amperometric detection on an electrode modified with a mesoporous nano‐structured carbon material

In this article, a carbon disk electrode modified with mesoporous carbon material (CMK‐3) was used in CE with amperometric detection system for the simultaneous determination of four types of important nitroaromatic compounds, including 2,4,6‐trinitrotoluene (TNT), 1,3,5‐trinitrobenzene (TNB), 2,4‐dinitrotoluene (DNT) and 1,3‐dinitrobenzene (DNB). Compared with the bare carbon electrode, the CMK‐3 modified electrode greatly improved the sensitivity at a relatively positive detection potential due to its excellent electrocatalytic activities, high conductivity and large effective surface area. The four analytes could be well separated and detected within 480 s. A good linear response was obtained for TNB, DNB, TNT and DNT from 8.4 to 5.0×10³ μg/L, with correlation coefficients higher than 0.9992. And the detection limits were established between 3.0 and 4.7 μg/L for the four investigated nitroaromatic compounds (S/N=3). The CMK‐3‐modified electrode was successfully employed to analyze coking wastewater, tap water and river samples with recoveries in the range of 94.8–109.0%, and RSDs less than 5.0%. The presented results demonstrated that the CMK‐3‐modified carbon electrode used in CE with amperometric detection was of convenient preparation, high sensitivity and good repeatability, which could be employed in the rapid determination of practical samples.     

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线性规划椭球算法若干改进结果

本文给出线性规划哈奇杨椭球算法的两个改进形式,推广了哈奇杨文的结果,给出了对解线性代数方程组的应用和若干数值算例。     

Hierarchical simultaneous entanglement swapping for multi-hop quantum communication based on multi-particle entangled states

Entanglement swapping is a key technology for multi-hop communication based on entanglement in quantum networks. However, the end-to-end delay of the traditional sequential entanglement swapping (SEQES) grows rapidly withthe increase of network scale. To solve this problem, we first propose a low-delay multi-particle simultaneous entanglementswapping (SES) scheme to establish the remote four-particle Greenberger–Horne–Zeilinger (GHZ) channel states for thebidirectional teleportation of three-particle GHZ states, in which the intermediate nodes perform Bell state measurements,send the measurement results and the Bell state type to the user node Bob (or Alice) through classical channel simultaneously. Bob (or Alice) only needs to carry out a proper unitary operation according to the information he (or she) hasreceived. Further, we put forward a hierarchical simultaneous entanglement swapping (HSES) scheme to reduce the classical information transmission cost, which is composed of level-1 SES and level-2 SES (schemes). The former is an innersegment SES, and the latter is an inter segments SES. Theoretical analysis and simulation results show the HSES can obtainthe optimal performance tradeoff between end-to-end delay and classical cost.